Allyl chloride → HCID 21946363, compound

HRID 1165419Notes

Reaction equation

HRID 1165419 reaction equation
[SiH4].[NH2:2][CH2:3][CH2:4][NH:5][CH2:6][CH2:7][CH2:8][Si:9]([O:14][CH3:15])([O:12][CH3:13])[O:10][CH3:11].[CH2:16]([Cl:19])[CH:17]=[CH2:18]>CO.[Cu]>[ClH:19].[CH2:18]([N:5]([CH2:4][CH2:3][NH2:2])[CH2:6][CH2:7][CH2:8][Si:9]([O:14][CH3:15])([O:10][CH3:11])[O:12][CH3:13])[CH:17]=[CH2:16]

Participants

6

Reactant 3

HCID 7850Allyl chlorideHCID 15659(Trimethoxysilylpropyl)ethylenediamineHCID 23953Silane

Product 1

HCID 21946363HCID 21946363, compound

Reagents, catalysts & solvents 2

HCID 23978CopperCatalystHCID 887MethanolSolvent

Procedure

Example 1 was repeated except that the copper foil was pretreated with a silane solution prepared as follows. 6.66 grams of N-2-aminoethyl-3-aminopropyltrimethoxysilane (a product of Petrarch Systems Inc.) in 886 g of methanol were charged in a reaction vessel with 2.29 grams of allyl chloride to produce 3-(N-allyl-2-aminoethylamino)-propyltrimethoxysilane hydrochloride. A 1% solution of this silane in methanol was prepared as described in Example 12 and the copper foil dipped for 30 minutes. The copper foil and lamination were performed as described in Example 12 at a psi of 1100. The prepregs (2-ply) had a 62.45% polymer uptake and were formed into 6"×6" 2-ply laminates.

Workup

  1. customprepared

Sources & evidence

ORD record
ord-7d7fcf89d9a64c93bf08d2f8dc076110
Source dataset
uspto-grants-1990_03
Patent number
US04910077

Reaction notes

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