Potassium Hydroxide → Potassium D-lyxonate

HRID 1165560Notes

Reaction equation

O=C[C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[OH-:13].[K+:14]>>[O:13]=[C:3]([O-:4])[C@H:5]([C@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6].[K+:14]

Participants

Reactant 2

HCID 14797Potassium Hydroxide

HCID 3037556(2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 23666384Potassium D-lyxonate

Procedure

oxidizing D-galactose in alcoholic KOH to open the pyranose ring and form potassium D-lyxonate,

Sources & evidence

ORD record: ord-e9e09f05cec6486b8701ebb058718c75
Source dataset: uspto-grants-1990_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04910310

Reaction notes

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