Methacrylic Acid → 2-Hydroxyethyl Methacrylate

HRID 1165595Notes

Reaction equation

HRID 1165595 reaction equation
[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH2:7]1[O:9][CH2:8]1>[Fe]>[OH:9][CH2:8][CH2:7][O:5][C:1](=[O:6])[C:2]([CH3:4])=[CH2:3]

Participants

4

Reactant 2

HCID 4093Methacrylic AcidHCID 6354Ethylene Oxide

Product 1

HCID 133602-Hydroxyethyl Methacrylate

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Conditions

Temperature
70 °C

Procedure

The procedure of Example 4 is repeated, except with less catalyst (1.9 g, 46% iron), with methacrylic acid (2.0 g) used in place of acrylic acid, and slightly less ethylene oxide added (3.8 g). The reactor is heated to 70° C. for 1 hour. The results for the product hydroxyethylmethacrylate (HEMA) are presented in Table 2.

Workup

  1. additionadded (3.8 g)

Sources & evidence

ORD record
ord-12bdf9ded56248dfa41a14511881a0e9
Source dataset
uspto-grants-1990_03
Patent number
US04910329

Reaction notes

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