Diethylamine → 1-Methoxycarbonyl-7-isopropylazulene

HRID 1165893Notes

Reaction equation

HRID 1165893 reaction equation
[CH3:1][O:2][C:3]([C:5]1[C:9](=O)O[C:7]2=[CH:11][CH:12]=[CH:13][C:14]([CH:16]([CH3:18])[CH3:17])=[CH:15][C:6]=12)=[O:4].[CH2:19](NCC)C>>[CH3:1][O:2][C:3]([C:5]1[C:6]2[C:7]([CH:11]=[CH:12][CH:13]=[C:14]([CH:16]([CH3:18])[CH3:17])[CH:15]=2)=[CH:19][CH:9]=1)=[O:4]

Participants

3

Reactant 2

HCID 8021DiethylamineHCID 100604625-Isopropyl-3-(methoxycarbonyl)-2H-cyclohepta[b]furan-2-one

Product 1

HCID 111388961-Methoxycarbonyl-7-isopropylazulene

Procedure

To a diethylamine (120 ml) suspension of 3-methoxycarbonyl-5-isopropyl-2H-cyclohepta[b]furan-2-one (16) (5.0 g) acetaldehyde (5.7 ml) was added.

Workup

  1. additionwas added

Sources & evidence

ORD record
ord-fcc09138ede142aa9313dea99ba36158
Source dataset
uspto-grants-1990_03
Patent number
US04912134

Reaction notes

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