Decanoic Acid → HCID 86583986, compound

HRID 1166030Notes

Reaction equation

HRID 1166030 reaction equation
[OH:1][C:2]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])=[O:3].[OH:13][CH2:14][C@@H:15]([C@H:17]([C@@H:19]([C@@H:21]([CH2:23][OH:24])[OH:22])[OH:20])[OH:18])[OH:16].C(O)(C)(C)C>O>[OH:3][C:2]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])=[O:1].[OH:3][C:2]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])=[O:1].[OH:24][CH2:23][C@@H:21]([C@H:19]([C@@H:17]([C@@H:15]([CH2:14][OH:13])[OH:16])[OH:18])[OH:20])[OH:22]

Participants

5

Reactant 3

HCID 2969Decanoic AcidHCID 5780Sorbitol2×HCID 6386tert-Butanol

Product 1

HCID 86583986HCID 86583986, compoundYield 1.6%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
35 °C

Procedure

A mixture of capric acid (0.86 g=5 mmole), sorbitol (0.91 g=5 mmole), t-butanol (500 μl), water (70 μl) and potato protein extract (100 mg) was stirred at 35° C. in a stoppered tube for 72 hours. Analysis of the resulting reaction mixture showed that sorbitol monocapric (0.12 mmoles) and sorbitol dicaprate (0.04 mmoles) were formed.

Workup

  1. extractionextract (100 mg)
  2. customAnalysis of the resulting reaction mixture

Sources & evidence

ORD record
ord-9d072438bed04d07878a58b28c784f91
Source dataset
uspto-grants-2003_09
Patent number
US06613551B2

Reaction notes

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