Trimethyl Phosphate → HCID 178502936, compound

HRID 1168024Notes

Reaction equation

HRID 1168024 reaction equation
[Cl-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[P:15](OC)([O:19][CH3:20])([O:17][CH3:18])=[O:16]>>[CH3:18][O:17][PH:15](=[O:16])[O:19][CH3:20].[C:9]1([I+:8][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Participants

3

Reactant 2

HCID 10541Trimethyl PhosphateHCID 73870Diphenyliodonium chloride

Product 1

HCID 178502936HCID 178502936, compoundYield 81.6%

Procedure

Diphenyliodonium chloride (315 mg; 1 mmol) and trimethyl phosphate (1 g) were stirred at 170° C. for 10 minutes. After the reactants were dissolved, the mixture was cooled, to thereby yield solid matter. The solid matter was washed with ether, to thereby yield 250 mg of the target compound as white crystals (yield: 81.6%). The anion content of the resultant compound was determined by ion chromatography. The chloride anion content was determined to be not greater than 10 ppm.

Workup

  1. dissolutionAfter the reactants were dissolved
  2. temperaturethe mixture was cooled
  3. customto thereby yield solid matter
  4. washThe solid matter was washed with ether

Sources & evidence

ORD record
ord-3964f1b467fd450cb3afcb2aab13d4d5
Source dataset
uspto-grants-2003_09
Patent number
US06620957B1

Reaction notes

Loading…