Triethyl Phosphate → HCID 178448396, compound

HRID 1168026Notes

Reaction equation

HRID 1168026 reaction equation
[Cl-].[C:2]([IH+:6]([C:13]([CH3:16])([CH3:15])[CH3:14])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)([CH3:5])([CH3:4])[CH3:3].[P:17]([O:25]CC)([O:22][CH2:23][CH3:24])([O:19][CH2:20][CH3:21])=[O:18]>>[CH2:20]([O:19][P:17]([O-:25])([O:22][CH2:23][CH3:24])=[O:18])[CH3:21].[C:13]([IH+:6]([C:2]([CH3:5])([CH3:4])[CH3:3])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)([CH3:16])([CH3:15])[CH3:14]

Participants

3

Reactant 2

HCID 6535Triethyl PhosphateHCID 178448397HCID 178448397, compound

Product 1

HCID 178448396HCID 178448396, compoundYield 91.5%

Conditions

Temperature
115 °C

Procedure

A solution containing di-tert-butylphenyliodonium chloride (443 mg; 1 mmol) and triethyl phosphate (3 g) was stirred at 110-120° C. for 1 hour. The thus-obtained solid matter was washed with ether, to thereby yield 432 mg of the target compound as white crystals (yield: 69.2%).

Workup

  1. washThe thus-obtained solid matter was washed with ether

Sources & evidence

ORD record
ord-aaef95135d264c25b33efc4e72280fec
Source dataset
uspto-grants-2003_09
Patent number
US06620957B1

Reaction notes

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