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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1168505Generated: November 3, 2026

Diethyl (ethoxymethylene)malonate → HCID 12083030, compound

https://huagongshe.com/reaction/1168505

Reaction equation

Participants

RoleNameHCIDCharge
ReactantDiethyl (ethoxymethylene)malonateHCID 6871—
Reactant2,2-diMethyl-2,3-dihydro-1H-indoleHCID 12437302—
ProductHCID 12083030HCID 12083030—

Reaction Conditions

Temperature105 °C

Reaction Steps

A mixture of 2,2-dimethylindoline (1.47 g) and diethyl ethoxymethylenemalonate (2.0 ml) is heated to 105° C. for 17 hours to afford the title compound as a pale yellow oil. Physical characteristics: 1H NMR (CDCl3) δ7.76, 7.18, 7.12, 6.97, 6.74, 4.24, 3.16, 1.50, 1.34.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06624159B2
Source datasetuspto-grants-2003_09
ORD IDord-62ec539d348e47e59aa4cc5914ae4f11
Source noteuspto-grants-2003_09