HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannous chloride dihydrate → HCID 42605101, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Reactant | HCID 59550643 | HCID 59550643 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 42605101 | HCID 42605101 | 86.1% |
Reaction Steps
In analogy to GP 3, reaction of 1.49 g trifluoromethanesulphonic acid 3-cyano-6-cyclopropyl-4-(4-nitro-phenyl)-pyridin-2-yl ester (3.6 mmol, 1 eq.) with 4.1 g tin(II) chloride dihydrate (18.19 mmol, 5 eq.) in 20 mL EtOH yielded 1.2 g of the desired aniline (3.1 mmol, 86% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07825114B2 |
| Source dataset | uspto-grants-2010_11 |
| ORD ID | ord-f99dbf05da134c52b91b72a6836e4a16 |
| Source note | uspto-grants-2010_11 |