m-Chloroperbenzoic acid → 2-Chloro-5-methanesulfinylpyridine

HRID 1171881Notes

Reaction equation

HRID 1171881 reaction equation
IF.[Cl:3][C:4]1[CH:9]=[CH:8][C:7]([S:10][CH3:11])=[CH:6][N:5]=1.C1C=C(Cl)C=C(C(OO)=[O:20])C=1>>[Cl:3][C:4]1[CH:9]=[CH:8][C:7]([S:10]([CH3:11])=[O:20])=[CH:6][N:5]=1

Participants

4

Reactant 3

HCID 70297m-Chloroperbenzoic acidHCID 139637Iodine fluoride (IF)HCID 234369232-Chloro-5-(methylthio)pyridine

Product 1

HCID 135878162-Chloro-5-methanesulfinylpyridine

Procedure

2-Chloro-5-methylsulfinylpyridine was prepared by the method described in Example I-F from 2-chloro-5-methylthiopyridine using mCPBA as oxidant.

Sources & evidence

ORD record
ord-9556fb9937a34b2ea6c8ae229a628cad
Source dataset
uspto-grants-2010_11
Patent number
US07829719B2

Reaction notes

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