HRID1172026

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[Br-].c1ccc([S+](c2ccccc2)c2ccccc2)cc1

HCID11984010

Triphenylsulfonium Bromide

C18H15BrS

结构：O=S(=O)(O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)S(=O)(=O)O

HCID13848002

Perfluorobutane-1,4-disulfonic acid

C4H2F8O6S2

结构：CC(=O)[O-].CC(=O)[O-].CC(C)(C)c1ccc([IH+])cc1.CC(C)(C)c1ccc([IH+])cc1

HCID131728420

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)c1ccc([IH+])cc1.CC(C)(C)c1ccc([IH+])cc1.O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)S(=O)(=O)[O-].c1ccc([S+](c2ccccc2)c2ccccc2)cc1

HCID131728419

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID180

Acetone

C3H6O

溶剂HCID962

Water

H2O

PROCEDURE

实验过程

4.73 g of triphenyl sulfonium bromide was dissolved in water in a flask. Bis (4-t-butylphenyl iodonium) acetate (6.24 g) was dissolved in acetone and added to the flask. Perfluorobutane-1,4-disulfonic acid (5.0 g) was then added to the mixture and the mixture was stirred over night at room temperature. Bis (4-t-butylphenyl iodonium) triphenyl sulfonium perfluorobutane-1,4-disulfonate was isolated as in Example 1 (mixture of compounds); mp 93° C.

WORKUP

后处理

additionadded to the flask

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-be4c57ae49ed44e29ea4157d11fc05d0
来源数据集: uspto-grants-2010_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07833693B2
来源说明: uspto-grants-2010_11

反应 SMILES

[Br-].[C:2]1([S+:8]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[C:25]([C:29]1[CH:34]=[CH:33][C:32]([IH+:35])=[CH:31][CH:30]=1)([CH3:28])([CH3:27])[CH3:26].[C:36]([C:40]1[CH:45]=[CH:44][C:43]([IH+:46])=[CH:42][CH:41]=1)([CH3:39])([CH3:38])[CH3:37].C([O-])(=O)C.[F:51][C:52]([F:70])([S:66]([OH:69])(=[O:68])=[O:67])[C:53]([F:65])([F:64])[C:54]([F:63])([F:62])[C:55]([F:61])([F:60])[S:56]([OH:59])(=[O:58])=[O:57]>O.CC(C)=O>[F:61][C:55]([F:60])([S:56]([O-:59])(=[O:58])=[O:57])[C:54]([F:63])([F:62])[C:53]([F:64])([F:65])[C:52]([F:51])([F:70])[S:66]([O-:69])(=[O:67])=[O:68].[C:15]1([S+:8]([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1.[C:25]([C:29]1[CH:30]=[CH:31][C:32]([IH+:35])=[CH:33][CH:34]=1)([CH3:28])([CH3:26])[CH3:27].[C:36]([C:40]1[CH:41]=[CH:42][C:43]([IH+:46])=[CH:44][CH:45]=1)([CH3:39])([CH3:37])[CH3:38]