HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylsulfonium Bromide → Bis (4-t-butylphenyl iodonium) triphenyl sulfonium perfluorobutane-1,4-disulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylsulfonium Bromide | HCID 11984010 | — |
| Reactant | 1,4-Butanedisulfonic acid, 1,1,2,2,3,3,4,4-octafluoro- | HCID 13848002 | — |
| Reactant | Bis (4-t-butylphenyl iodonium) acetate | HCID 131728420 | — |
| Solvent | Acetone | HCID 180 | — |
| Solvent | Water | HCID 962 | — |
| Product | Bis (4-t-butylphenyl iodonium) triphenyl sulfonium perfluorobutane-1,4-disulfonate | HCID 131728419 | — |
Reaction Steps
4.73 g of triphenyl sulfonium bromide was dissolved in water in a flask. Bis (4-t-butylphenyl iodonium) acetate (6.24 g) was dissolved in acetone and added to the flask. Perfluorobutane-1,4-disulfonic acid (5.0 g) was then added to the mixture and the mixture was stirred over night at room temperature. Bis (4-t-butylphenyl iodonium) triphenyl sulfonium perfluorobutane-1,4-disulfonate was isolated as in Example 1 (mixture of compounds); mp 93° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07833693B2 |
| Source dataset | uspto-grants-2010_11 |
| ORD ID | ord-be4c57ae49ed44e29ea4157d11fc05d0 |
| Source note | uspto-grants-2010_11 |