Toluene → 2,3,5-Triiodobenzoic acid
Reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].CCCCCCCCCC(C)C.C1(C)C=CC=CC=1>>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]Participants
3
Procedure
21.8 mL of TIBA/isododecane solution (110 g/L) were mixed with 5 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.928 g/mL, 24 mmol MAO) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 30 min at room temperature and transferred into a 50 mL Schlenk flask containing C-2 (49.6 mg, 60.4 μmol). The final solution was diluted with 11.7 mL of isododecane to form a dark orange/red solution after overnight stirring at room temperature (final concentration=100 gTOT/L and 1.29 gmetallocene/L).
Sources & evidence
- ORD record
- ord-1c493de22818490082f9096e241db05c
- Source dataset
- uspto-grants-2010_11
- Patent number
- US07834205B2
Reaction notes
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