Toluene → 2,3,5-Triiodobenzoic acid

Participants

Reaction Steps

21.8 mL of TIBA/isododecane solution (110 g/L) were mixed with 5 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.928 g/mL, 24 mmol MAO) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 30 min at room temperature and transferred into a 50 mL Schlenk flask containing C-2 (49.6 mg, 60.4 μmol). The final solution was diluted with 11.7 mL of isododecane to form a dark orange/red solution after overnight stirring at room temperature (final concentration=100 gTOT/L and 1.29 gmetallocene/L).

Provenance & Evidence