4-Hydroxybiphenyl → Carbamic acid, methylphenyl-, [1,1'-biphenyl]-4-yl ester

HRID 1179721Notes

Reaction equation

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[CH3:14][N:15]([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)[C:16](Cl)=[O:17]>>[C:5]1([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:4]=[CH:3][C:2]([O:1][C:16](=[O:17])[N:15]([CH3:14])[C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)=[CH:7][CH:6]=1

Participants

Reactant 2

HCID 71034-Hydroxybiphenyl

HCID 77969Carbamic chloride, N-methyl-N-phenyl-

Product 1

HCID 10171795Carbamic acid, methylphenyl-, [1,1'-biphenyl]-4-yl ester

Procedure

The title compound was prepared from 4-hydroxybiphenyl and N-methyl-N-phenylcarbamoyl chloride applying. The crude product was recrystallized (ethanol) (75%, white crystals).

Workup

customThe crude product was recrystallized (ethanol) (75%, white crystals)

Sources & evidence

ORD record: ord-0e327dd27e1a4416872aff3062cdaef9
Source dataset: uspto-grants-2007_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07279470B2

Reaction notes

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