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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1180467Generated: November 1, 2026

Carbamic acid, ethyl ester → Toluene 2,4-Diisocyanate

https://huagongshe.com/reaction/1180467

Reaction equation

Participants

RoleNameHCIDCharge
ReactantCarbamic acid, ethyl esterHCID 5641—
ReactantIsocyanateHCID 105034—
ReactantHCID 21226399HCID 21226399—
ProductToluene 2,4-DiisocyanateHCID 11443—
ProductHexamethylene diisocyanateHCID 13192—

Reaction Conditions

Temperature80 °C

Reaction Steps

As the adhesive layer, a polyester-urethane adhesive was used and a composition for an adhesive layer was prepared as follows. That is, a polyester resin (80 parts by weight, VYLON RV-200) manufactured by Toyo Boseki Kabushiki Kaisha was dissolved in a mixed solvent (1940 parts by weight) of toluene/methyl ethyl ketone=80/20 (weight ratio) while heating at 80° C. After cooling, DESMODUER HL (20 parts by weight, manufactured by Sumitomo Bayer Urethane) which is isocyanulate polyhydric isocyanate obtained from hexamethylene diisocyanate and toluene diisocyanate as starting materials, was added as isocyanulate polyhydric isocyanate, and triethylene diamine (0.06 part by weight) was added as a curing catalyst, and the mixture was stirred for 10 min.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS07282256B2
Source datasetuspto-grants-2007_10
ORD IDord-8659fbfd7f1f433a9d32e19c4317adcd
Source noteuspto-grants-2007_10