Potassium Carbonate → HCID 3746339, compound

HRID 1181614Notes

Reaction equation

HRID 1181614 reaction equation
[F:1][C:2]1[C:7]([S:8](F)(=[O:10])=[O:9])=[C:6]([F:12])[C:5]([F:13])=[C:4]([F:14])[C:3]=1[F:15].C(=O)([O-])[O-:17].[K+:20].[K+]>O>[F:1][C:2]1[C:7]([S:8]([O-:17])(=[O:10])=[O:9])=[C:6]([F:12])[C:5]([F:13])=[C:4]([F:14])[C:3]=1[F:15].[K+:20]

Participants

4

Reactant 2

HCID 11430Potassium Carbonate2×HCID 11807055pentafluorobenzenesulfonyl fluoride

Product 1

HCID 3746339HCID 3746339, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

25 Grams (93.8 mmols) of pentafluorobenzenesulfonyl fluoride was charged in a flask, and 13.0 g (93.8 mmols) of potassium carbonate and 100 ml of water were added under cooling with ice, followed by stirring at room temperature for 9 hours. Then, 1.3 g (9.4 mmols) of potassium carbonate was further added and the mixture was stirred at 60° C. for 1 hour. A white solid produced was filtered off and purified by recrystallization with water. The resulting white solid was subjected to 19F-NMR measurement and it was confirmed that the resulting white solid was potassium pentafluorobenzenesulfonate (c).

Workup

  1. temperatureunder cooling with ice
  2. stirringthe mixture was stirred at 60° C. for 1 hour
  3. customA white solid produced
  4. filtrationwas filtered off
  5. custompurified by recrystallization with water

Sources & evidence

ORD record
ord-6a785fcbbd184a5ba2dc58031c452ee0
Source dataset
uspto-grants-2007_10
Patent number
US07285616B2

Reaction notes

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