HCID 87313423, compound → HCID 87148504, compound

HRID 1182420Notes

Reaction equation

HRID 1182420 reaction equation
[C:1](=[N:5][C:6]1[C:11]([CH2:12][CH3:13])=[CH:10][C:9]([CH2:14][CH3:15])=[C:8]([N:16]=[C:17]([CH2:19][CH3:20])[CH3:18])[C:7]=1[CH3:21])([CH2:3][CH3:4])[CH3:2]>[Pt].CC(C)=O>[CH:17]([NH:16][C:8]1[C:9]([CH2:14][CH3:15])=[CH:10][C:11]([CH2:12][CH3:13])=[C:6]([NH:5][CH:1]([CH2:3][CH3:4])[CH3:2])[C:7]=1[CH3:21])([CH2:19][CH3:20])[CH3:18]

Participants

4

Reactant 1

HCID 87313423HCID 87313423, compound

Product 1

HCID 87148504HCID 87148504, compound

Reagents, catalysts & solvents 2

HCID 23939PlatinumCatalystHCID 180AcetoneSolvent

Procedure

N,N′-di-sec-butylidene-[diethyl(methyl)-1,3-benzenediamine] (28 g) and Pt(S)/C (2.8 g) were added to acetone (30 g) in an autoclave. The closed autoclave was purged 3 times with 125 psig (9.63×105 Pa) of H2 at 22° C. The mixture was kept at 21° C. and 125 psi (8.62×105 Pa) of H2 for 12 hours, forming the corresponding N,N′-di-sec-butyl-[diethyl(methyl)-1,3-benzenediamine] quantitatively.

Workup

  1. customThe closed autoclave was purged 3 times with 125 psig (9.63×105 Pa) of H2 at 22° C
  2. customwas kept at 21° C.

Sources & evidence

ORD record
ord-714fa2e3584f49ba9bda2e9a4d7f756d
Source dataset
uspto-grants-2007_10
Patent number
US07288677B2

Reaction notes

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