Dimethylamine → HCID 19990247, compound

HRID 1185336Notes

Reaction equation

Cl[C:2]1[N:6]([CH3:7])[N:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9].[CH3:11][NH:12][CH3:13]>>[CH3:11][N:12]([CH3:13])[C:2]1[N:6]([CH3:7])[N:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9]

Participants

Reactant 2

HCID 674Dimethylamine

HCID 123448365-chloro-1-methyl-4-nitro-1H-pyrazole

Product 1

HCID 19990247HCID 19990247, compoundYield 100%

Procedure

Reaction of 5-chloro-1-methyl-4-nitro-1H-pyrazole and dimethylamine gave N,N,1-trimethyl-4-nitro-1H-pyrazol-5-amine as a yellow solid (210 g, 100%). 1H NMR (400 MHz, CDCl3) δ 8.01 (s, 1H), 3.75 (s, 3H), 2.90 (s, 6H)

Sources & evidence

ORD record: ord-c3f20e1dfd284f2aaf93700e1c4882d1
Source dataset: uspto-grants-2014_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08669361B2

Reaction notes

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