Trimethylsilyldiazomethane → Methyl 2-(2,4-dinitrophenyl)acetate

HRID 1185965노트

반응식

HRID 1185965 반응식
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[CH2:13][C:14]([OH:16])=[O:15])([O-:3])=[O:2].[CH3:17][Si](C=[N+]=[N-])(C)C>>[CH3:17][O:15][C:14](=[O:16])[CH2:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2]

참가 물질

3

반응물 2

HCID 167693TrimethylsilyldiazomethaneHCID 2215132,4-Dinitrophenylacetic acid

생성물 1

HCID 286146Methyl 2-(2,4-dinitrophenyl)acetate

실험 절차

2,4-diaminophenylacetic acid methyl ester is obtained by reacting 2,4-dinitrophenylacetic acid with trimethylsilyldiazomethane to obtain 2,4-dinitrophenylacetic acid methyl ester, followed by reducing 2,4-dinitrophenylacetic acid methyl ester using a strong reducing agent.

출처 및 근거

ORD 기록
ord-81851434d0124e648183b204fc35fc39
출처 데이터셋
uspto-grants-2014_03
특허 번호
US08673177B2

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