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HRID1186658

反应详情

EQUATION

反应方程式

HRID 1186658 的结构方程式

REACTANTS

反应物

2
结构：NS(=O)(=O)Cc1ccc(Cl)cc1
HCID581056

(4-Chlorophenyl)methanesulfonamide

C7H8ClNO2S

结构：CCOC(=O)CSC1=C/C(=N\S(=O)(=O)c2cccs2)c2ccccc2C1=O
HCID58398202

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)CSC1=CC(=NS(=O)(=O)Cc2ccc(Cl)cc2)c2ccccc2C1=O
HCID67330733

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Cl][Ti]([Cl])([Cl])[Cl]
催化剂HCID24193

Titanium tetrachloride

Cl4Ti

结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

5.2.21 Ethyl 2-(4-(4-chlorobenzylsulfonylimino)-1-oxo-1,4-dihydronaphthalen-2-ylthio)-acetate (8g) was prepared according to the procedure for 8a except using (4-chlorophenyl)methanesulfonamide, TiCl4.2THF and THF as solvent. The title compound 130 mg (56%) was obtained according to the workup procedure for 12a as a yellow solid, m.p.: ° C.