HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 2-bromo-5-methoxybenzoate → HCID 58121105, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 2-bromo-5-methoxybenzoate | HCID 2776849 | — |
| Reactant | Methyl 3-chloro-5-phenylthiophene-2-carboxylate | HCID 58121069 | — |
| Product | HCID 58121105 | HCID 58121105 | 90% |
Reaction Steps
The procedure was followed as outlined in Scheme 2, Step 1 replacing compounds 8 and 9 with compounds 83 and 84 to afford methyl 3,5-diphenylthiophene-2-carboxylate 85 (90% yield) as a white solid after purification by ISCO (12 g column, 0 to 30% ethyl acetate in hexane). LRMS (ESI): (calc) 294.37 (found) 295.21 (MH)+
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08673911B2 |
| Source dataset | uspto-grants-2014_03 |
| ORD ID | ord-5d98b22541e741079afee4195bf6f0bd |
| Source note | uspto-grants-2014_03 |