HCID 66688801, compound → 1-Butyl-3-methyl-imidazolium valerate

HRID 1189597Notes

Reaction equation

HRID 1189597 reaction equation
C([O-])(=O)C.[CH2:5]([N+:9]1[CH:13]=[CH:12][N:11]([CH3:14])[CH:10]=1)[CH2:6][CH2:7][CH3:8].[C:15]([O:21]C1C=CC([N+]([O-])=O)=CC=1CC(C1C=CC(OC)=CC=1)=O)(=[O:20])[CH2:16][CH2:17][CH2:18][CH3:19]>>[C:15]([O-:21])(=[O:20])[CH2:16][CH2:17][CH2:18][CH3:19].[CH2:5]([N+:9]1[CH:13]=[CH:12][N:11]([CH3:14])[CH:10]=1)[CH2:6][CH2:7][CH3:8]

Participants

3

Reactant 2

HCID 66688801HCID 66688801, compoundHCID 1784762761-Butyl-3-methylimidazolium Acetate

Product 1

HCID 1784475361-Butyl-3-methyl-imidazolium valerate

Procedure

The reaction was also carried out using 0.14 g (0.59 mmol) of the commercially available 1-butyl-3-methyl-imidazolium acetate with 0.11 g (0.29 mmol) of 2-(2-pentanoyloxy-5-nitrophenyl)-1-(4-methoxyphenyl)-ethanone (example 2) under the same reaction conditions as described in example 18. By comparing the LC-MS chromatogram of the crude reaction mixture with the chromatogram obtained from the reaction with 1-butyl-3-methyl-imidazolium valerate it was concluded that both methods delivered the targed compound in similar yield.

Workup

  1. customunder the same reaction conditions
  2. customreaction mixture with the chromatogram

Sources & evidence

ORD record
ord-64881362461c48688c40846f3ab466b4
Source dataset
uspto-grants-2014_03
Patent number
US08674121B2

Reaction notes

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