Tetrahydrofuran → HCID 131731271, compound

HRID 1192853Notes

Reaction equation

HRID 1192853 reaction equation
[I-:1].[Ce+3:2].[I-].[I-].[C:5]([C:9]1[N-:10][C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])=[C:12]([C:14]([CH3:18])([CH3:17])[CH2:15][CH3:16])[N:13]=1)([CH3:8])([CH3:7])[CH3:6].[K+].[CH2:25]1[CH2:29][O:28][CH2:27][CH2:26]1>>[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[I-:1].[I-:1].[C:5]([C:9]1[N-:13][C:12]([C:14]([CH3:17])([CH3:18])[CH2:15][CH3:16])=[C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])[N:10]=1)([CH3:8])([CH3:7])[CH3:6].[Ce+3:2]

Participants

4

Reactant 3

HCID 8028TetrahydrofuranHCID 25021391Cerium(III) iodideHCID 131731268HCID 131731268, compound

Product 1

HCID 131731271HCID 131731271, compound

Procedure

Cerium (III) iodide (2.0 g, 0.0038 mol) was stirred in 50 mL of dry THF for 30 mins at room temperature. Potassium 2-tert-butyl-4,5-di(1,1-dimethylpropyl)imidazolate (1.15 g, 0.0038 mol) was added, and the resulting mixture was refluxed for 90 hours. The solvent was removed by vacuum, followed by hexane extraction of the resulting solid. The hexane was removed by vacuum to yield the final product.

Workup

  1. temperaturethe resulting mixture was refluxed for 90 hours
  2. customThe solvent was removed by vacuum
  3. extractionfollowed by hexane extraction of the resulting solid
  4. customThe hexane was removed by vacuum

Sources & evidence

ORD record
ord-8543db71a0cc4c0599446ed666e79db0
Source dataset
uspto-grants-2014_03
Patent number
US08680289B2

Reaction notes

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