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HRID1192976

反应详情

EQUATION

反应方程式

HRID 1192976 的结构方程式

REACTANTS

反应物

2
结构：C=C[Si](C)(C=C)c1ccccc1
HCID594382

methylphenyldivinylsilane

C11H14Si

结构：C#C[Si](C(C)C)(C(C)C)C(C)C
HCID2734682

(Triisopropylsilyl)acetylene

C11H22Si

PRODUCTS

生成物

1
结构：CC(C)[Si](C#C[SiH](C)C=Cc1ccccc1)(C(C)C)C(C)C
HCID123548403

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

As in reaction conditions of Example XIX Step 1, to 2.12 mL of toluene, the 0.02 g carbonylchlorohydridebis(tricyclohexylphosphine)ruthenium(II) was added, and the reaction was carried out between 2.88 g methylphenyldivinylsilane and 0.50 g ethynyltri(isopropyl)silane. Raw [(tri(isopropyl)silyl)ethynyl]methylphenylvinylsilane was obtained.

WORKUP

后处理

  1. customAs in reaction conditions of Example XIX Step 1