HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methylphenyldivinylsilane → [(Tri(isopropyl)silyl)ethynyl]methylphenylvinylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methylphenyldivinylsilane | HCID 594382 | — |
| Reactant | (Triisopropylsilyl)acetylene | HCID 2734682 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | [(Tri(isopropyl)silyl)ethynyl]methylphenylvinylsilane | HCID 123548403 | — |
Reaction Steps
As in reaction conditions of Example XIX Step 1, to 2.12 mL of toluene, the 0.02 g carbonylchlorohydridebis(tricyclohexylphosphine)ruthenium(II) was added, and the reaction was carried out between 2.88 g methylphenyldivinylsilane and 0.50 g ethynyltri(isopropyl)silane. Raw [(tri(isopropyl)silyl)ethynyl]methylphenylvinylsilane was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08680310B2 |
| Source dataset | uspto-grants-2014_03 |
| ORD ID | ord-790ad0921a874f30855f76be24215ee5 |
| Source note | uspto-grants-2014_03 |