Toluene → HCID 131731272, compound

HRID 1192979Notes

Reaction equation

HRID 1192979 reaction equation
CC(C)=[CH:3][SiH2:4][CH2:5][CH2:6][SiH2:7][CH:8]=[C:9]([CH3:11])[CH3:10].[CH3:13][C:14]([O:19][Si:20]([CH3:23])([CH3:22])[CH3:21])([CH2:17][CH3:18])[C:15]#[CH:16].[C:24]1(C)C=CC=CC=1>>[CH3:13][C:14]([O:19][Si:20]([CH3:22])([CH3:23])[CH3:21])([CH2:17][CH3:18])[C:15]#[C:16][Si:4]([CH3:3])([CH3:24])[CH2:5][CH2:6][SiH2:7][CH:8]=[C:9]([CH3:10])[CH3:11]

Participants

4

Reactant 3

HCID 1140TolueneHCID 15581391Trimethyl[(3-methylpent-1-yn-3-yl)oxy]silaneHCID 131731273HCID 131731273, compound

Product 1

HCID 131731272HCID 131731272, compound

Procedure

As in reaction conditions of Example XIX Step 1, to 3.29 mL of toluene, the 0.02 g carbonylchlorohydridebis(tricyclohexylphosphine)ruthenium(H) was added, and the reaction was carried out between 1.64 g 1,2-bis(dimethylvinylsilyl)ethane and 0.47 g 3-methyl-3-(trimethylsiloxy)pent-1-yne. Raw 1-{[3-methyl-3-(trim ethyl siloxy)-1-pentynyl]dimethylsilyl}-2-(dimethylvinylsilyl)ethane was obtained.

Workup

  1. customAs in reaction conditions of Example XIX Step 1

Sources & evidence

ORD record
ord-c4216357105e40bf9252fabcea15fa30
Source dataset
uspto-grants-2014_03
Patent number
US08680310B2

Reaction notes

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