Toluene → HCID 67034799, compound

HRID 1192983Notes

Reaction equation

HRID 1192983 reaction equation
[CH3:1][Si:2]([CH3:11])([CH:9]=[CH2:10])[NH:3][Si:4]([CH3:8])([CH3:7])[CH:5]=[CH2:6].C([C:14]1([O:20][Si:21]([CH3:24])([CH3:23])[CH3:22])CCCCC1)#C.[C:25]1(C)[CH:30]=[CH:29]C=[CH:27][CH:26]=1>>[CH3:22][Si:21]([CH3:23])([CH3:24])[O:20][C:14]#[C:6][C:5]1([Si:4]([CH3:8])([CH3:7])[NH:3][Si:2]([CH3:1])([CH3:11])[CH:9]=[CH2:10])[CH2:29][CH2:30][CH2:25][CH2:26][CH2:27]1

Participants

4

Reactant 3

HCID 1140TolueneHCID 82126Silanamine, 1-ethenyl-N-(ethenyldimethylsilyl)-1,1-dimethyl-HCID 552482Silane, [(1-ethynylcyclohexyl)oxy]trimethyl-

Product 1

HCID 67034799HCID 67034799, compound

Procedure

As in reaction conditions of Example XIX Step 1, to 4.69 mL of toluene, the 0.02 g carbonylchlorohydridebis(triisopropylphosphine)ruthenium(II) was added, and the reaction was carried out between 2.29 g 1,1,3,3-tetramethyl-1,3-divinyldisilazane and 0.81 g 1-ethynyl-1-(trimethylsiloxy)cyclohexane. Raw 1-[(1-trimethylsiloxy-1-ethynyl)cyclohexyl]-1,1,3,3-tetramethyl-3-vinyldisilazane was obtained.

Workup

  1. customAs in reaction conditions of Example XIX Step 1

Sources & evidence

ORD record
ord-47fd03e2b644441db30c1bc31c918779
Source dataset
uspto-grants-2014_03
Patent number
US08680310B2

Reaction notes

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