m-Chloroperbenzoic acid → 4-(4,5-Epoxypentoxy)-4'-nitrobiphenyl

HRID 1193460Notes

Reaction equation

HRID 1193460 reaction equation
[CH2:1]([O:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[CH:15][CH:14]=2)=[CH:9][CH:8]=1)[CH2:2][CH2:3][CH:4]=[CH2:5].ClC1C=CC=C(C(OO)=[O:30])C=1>C(Cl)Cl>[O:30]1[CH2:5][CH:4]1[CH2:3][CH2:2][CH2:1][O:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]2[CH:14]=[CH:15][C:16]([N+:19]([O-:21])=[O:20])=[CH:17][CH:18]=2)=[CH:9][CH:8]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 199012844-(4-Pentenoxy)-4'-nitrobiphenyl

Product 1

HCID 221630194-(4,5-Epoxypentoxy)-4'-nitrobiphenyl

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Conditions

Temperature
0 °C

Procedure

To 250 ml of methylene chloride is added 28.3 g of 4-(4-penteneoxy)-4'-nitrobiphenyl. The solution is cooled to 0° C., and 18 g of meta-chloroperbenzoic acid is added slowly. The mixture is stirred at 0° C. for 24 hours, and allowed to warm to room temperature.

Workup

  1. temperatureto warm to room temperature

Sources & evidence

ORD record
ord-9be6f5f1ab5b4b5da18bd918b51b53e2
Source dataset
uspto-grants-1989_03
Patent number
US04810338

Reaction notes

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