Benzyl Isothiocyanate → HCID 178527990, compound

HRID 1193595Notes

Reaction equation

[CH2:1]([N:8]=[C:9]=[S:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N-:11]=[N+:12]=[N-:13].[Na+]>>[CH2:1]([N:8]1[C:9]([SH:10])=[N:13][N:12]=[N:11]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 2346Benzyl Isothiocyanate

HCID 33557Sodium Azide

Product 1

HCID 178527990HCID 178527990, compoundYield 7%

Procedure

Benzyl isothiocyanate (0.020 mol) and sodium azide (0.030 mol) were reacted substantially as described in Example 1C above to yield 0.27 g (7%) white needles: mp 141°-142° (chloroform/pet. ether).

Sources & evidence

ORD record: ord-9ce73d8b13fc4f21be8bbebff5c94004
Source dataset: uspto-grants-1989_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04810811

Reaction notes

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