HuagongsheHuagongshe Chemistry Print Report · For research reference only
Anisole → HCID 178503585, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Anisole | HCID 7519 | — |
| Reactant | Methyl triflate | HCID 9526 | — |
| Reactant | 6-Methyl-2-(methylsulfanyl)cyclohepta[d]imidazole | HCID 20064375 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 178503585 | HCID 178503585 | — |
Reaction Steps
6-Methyl-2-methylthiocycloheptimidazole (27 g) was added to 100 ml of anisole and stirred under ice cooling. Then, 28 g of methyl trifluoromethanesulfonate was added dropwise thereto, and stirred under ice cooling. The mixture was further stirred at room temperature for one hour, 200 ml of ethyl acetate was added, and deposited crystals were collected by filtration and dried.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04814265 |
| Source dataset | uspto-grants-1989_03 |
| ORD ID | ord-75cb94b97c944c6da485b398bf71388d |
| Source note | uspto-grants-1989_03 |