HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromobenzene → Ethyl 3-phenylprop-2-enoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromobenzene | HCID 7961 | — |
| Reactant | Ethyl Acrylate | HCID 8821 | — |
| Reactant | Iodobenzene | HCID 11575 | — |
| Reactant | Iodide Ion | HCID 30165 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | Ethyl 3-phenylprop-2-enoate | HCID 7649 | — |
Reaction Steps
More specifically, we have found that chlorobenzene reacts with ethyl acrylate to form ethyl cinnamate in relatively high yield by reacting the chlorobenzene with iodide and/or bromide ion to form a mixture of chlorobenzene, iodobenzene and/or bromobenzene, then reacting the mixture with ethyl acrylate in the presence of a catalyst to form ethyl cinnamate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04814489 |
| Source dataset | uspto-grants-1989_03 |
| ORD ID | ord-6f72a208a7344acea8fc457e2fec1a80 |
| Source note | uspto-grants-1989_03 |