Glycidol → HCID 86740360, compound

HRID 1194624Notes

Reaction equation

HRID 1194624 reaction equation
[CH2:1]([NH2:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:20]1[O:22][CH:21]1[CH2:23][OH:24]>C1(C)C=CC=CC=1>[CH2:1]([NH2:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH:24][CH2:23][CH:21]([OH:22])[CH3:20]

Participants

4

Reactant 2

HCID 11164GlycidolHCID 15793Octadecylamine

Product 1

HCID 86740360HCID 86740360, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
60 °C

Procedure

Approximately 280 g of octadecylamine and about 0.35 liter of toluene were charged to a glass reactor and warmed to about 60° C. Over a 3 hour period of time, 38 g of glycidol were slowly added in small increments with agitation while maintaining a temperature of 60° to 65° C. The reactor contents were then heated at about 90° C. for 26 additional hours. The solvent was removed by vacuum distillation and the resulting product formed a pale yellow waxy solid after cooling.

Workup

  1. temperaturewhile maintaining a temperature of 60° to 65° C
  2. temperatureThe reactor contents were then heated at about 90° C. for 26 additional hours
  3. customThe solvent was removed by vacuum distillation
  4. customthe resulting product formed a pale yellow waxy solid
  5. temperatureafter cooling

Sources & evidence

ORD record
ord-03e249b0f2cb4dac9e0d03140895edde
Source dataset
uspto-grants-1989_03
Patent number
US04816037

Reaction notes

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