HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromo-2-methylpropane → HCID 140352835, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromo-2-methylpropane | HCID 6555 | — |
| Reactant | (Z)-Ethyl 2-(hydroxyimino)-2-(2-(tritylamino)thiazol-4-yl)acetate hydrochloride | HCID 9589415 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | HCID 140352835 | HCID 140352835 | — |
Reaction Steps
Ethyl (Z)-2-(hydroxyimino)-2-(2-tritylaminothiazol-4-yl)acetate hydrochloride (1 g) was alkylated with 1-bromo-2-methylpropane (0.48 ml) as described in Example 5a to give the title compound (0.8 g), νmax (CHCl3) 3400, 2960, 1725, 1520 and 1025 cm-1 m; δH (CDCl3) 1.09 (6H, d, J 7 Hz), 1.30 (3H, t), 1.90 (1H, m), 3.95 (2H, d, J 7 Hz), 4.30 (2H, q), 6.42 (1H, s), 6.93 (1H, br.s), 7.22 (15H, m). [Mass spectrum: +ve ion (3NOBA) MH+ (514)].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04816452 |
| Source dataset | uspto-grants-1989_03 |
| ORD ID | ord-acba8d3d00b7430c8fbbd89b492400c4 |
| Source note | uspto-grants-1989_03 |