Sulfuryl chloride → HCID 178476606, compound

HRID 1194937Notes

Reaction equation

HRID 1194937 reaction equation
[C:1]([O:4][C@H:5]1[CH2:10][CH2:9][C@H:8]([O:11]/[N:12]=[C:13](/[C:21](=[O:23])[CH3:22])\[C:14]([O:16]C(C)(C)C)=[O:15])[CH2:7][CH2:6]1)(=[O:3])[CH3:2].S(Cl)([Cl:27])(=O)=O>C(O)(=O)C>[C:1]([O:4][C@H:5]1[CH2:10][CH2:9][C@H:8]([O:11]/[N:12]=[C:13](/[C:21](=[O:23])[CH2:22][Cl:27])\[C:14]([OH:16])=[O:15])[CH2:7][CH2:6]1)(=[O:3])[CH3:2]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 178476604HCID 178476604, compound

Product 1

HCID 178476606HCID 178476606, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

tert-Butyl (Z)-2-(trans -4-acetoxycyclohexyloxyimino)3-oxobutyrate (327 mg, 1 mmol) was reacted with sulphuryl chloride (0.8 ml) in glacial acetic acid (2 ml) by an analogous procedure to that described in Example 57d to give the crude title compound.

Sources & evidence

ORD record
ord-a47914208ac44cdea433a2dfcd993cf7
Source dataset
uspto-grants-1989_03
Patent number
US04816452

Reaction notes

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