HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Dinitrobenzene → 2-(4-Methylphenyl)-2-[4-(3-nitrophenoxy)phenyl]hexafluoropropane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Dinitrobenzene | HCID 7452 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-(4-Hydroxyphenyl)-2-(4-methylphenyl)hexafluoropropane | HCID 14832325 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-(4-Methylphenyl)-2-[4-(3-nitrophenoxy)phenyl]hexafluoropropane | HCID 14832335 | — |
Reaction Steps
334 g (1 mol) of 2-(4-hydroxyphenyl)-2-(4-methylphenyl)hexafluoropropane were dissolved in 1.5 dm3 of dimethylformamide, 276 g of potassium carbonate and 170 g (1.01 mol) of m-dinitrobenzene were added, and the mixture was refluxed for 24 hours. The dimethylformamide was subsequently removed by distillation, and the residue was recrystallized from methanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05110983 |
| Source dataset | uspto-grants-1992_05 |
| ORD ID | ord-dabbb03094404ab88be099900be87ada |
| Source note | uspto-grants-1992_05 |