Hydrochloric Acid → HCID 178517464, compound

HRID 1195797Notes

Reaction equation

HRID 1195797 reaction equation
C(OC([C:6]1[CH:15]=[CH:14][CH:13]=[CH:12][C:7]=1[C:8](=[N:10][OH:11])[NH2:9])=O)C.[OH-].[Na+].O.Cl.[CH2:20]([OH:22])C>>[C:7]1([C:8]2[N:9]=[C:20]([OH:22])[O:11][N:10]=2)[CH:6]=[CH:15][CH:14]=[CH:13][CH:12]=1

Participants

6

Reactant 5

HCID 313Hydrochloric AcidHCID 702EthanolHCID 962WaterHCID 14798Sodium HydroxideHCID 86745772o-Ethoxycarbonylbenzamidoxime

Product 1

HCID 178517464HCID 178517464, compound

Procedure

In accordance with the known process [Yakugaku Zasshi, 84(11), 1061 (1964)], 27 g (0.13 mol) of o-ethoxycarbonylbenzamidoxime were added to a liquid mixture consisting of 10 g (0.25 mol) of sodium hydroxide, 600 ml of water and 150 ml of ethyl alcohol, followed by stirring at room temperature for 3 hours. The reaction mixture was neutralized with dilute hydrochloric acid. Crystals thus formed were collected by filtration and then washed with water, whereby the title compound was obtained as colorless crystals.

Workup

  1. customCrystals thus formed
  2. filtrationwere collected by filtration
  3. washwashed with water, whereby the title compound
  4. customwas obtained as colorless crystals

Sources & evidence

ORD record
ord-e22460fb67da459bae8a00d8edab3b9d
Source dataset
uspto-grants-1992_05
Patent number
US05112841

Reaction notes

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