Benzoyl Peroxide → HCID 14368704, compound

HRID 1195834Notes

Reaction equation

HRID 1195834 reaction equation
[F:1][C:2]1[CH:11]=[C:10]([F:12])[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH3:13].[Br:14]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[F:1][C:2]1[CH:11]=[C:10]([F:12])[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH2:13][Br:14]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 14368703HCID 14368703, compound

Product 1

HCID 14368704HCID 14368704, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

1.35 g of 5,7-Difluoro-1-methylnaphthaline in 10 ml of carbon tetrachloride are refluxed for 41/2 hours with 1.4 g of N-bromosuccinimide and 50 mg of dibenzoylperoxide. The cooled mixture is filtered and the solvent removed under vacuum. The purity of the crystalline crude product is sufficient for further reaction, m.p. 74°-76.5°.

Workup

  1. filtrationThe cooled mixture is filtered
  2. customthe solvent removed under vacuum
  3. customThe purity of the crystalline crude product is sufficient for further reaction, m.p. 74°-76.5°

Sources & evidence

ORD record
ord-8c79336066a24a918e8010e041886d60
Source dataset
uspto-grants-1992_05
Patent number
US05112851

Reaction notes

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