Dichloromethane → HCID 19896631, compound

HRID 1196866Notes

Reaction equation

HRID 1196866 reaction equation
[CH3:1][S:2][C:3]1[CH:12]=[CH:11][C:6]([CH2:7][N:8]=[N+:9]=[N-:10])=[CH:5][CH:4]=1.C(Cl)[Cl:14]>>[Cl:14][CH2:1][S:2][C:3]1[CH:12]=[CH:11][C:6]([CH2:7][N:8]=[N+:9]=[N-:10])=[CH:5][CH:4]=1

Participants

3

Reactant 2

HCID 6344DichloromethaneHCID 19896626HCID 19896626, compound

Product 1

HCID 19896631HCID 19896631, compound

Conditions

Temperature
5 °C

Procedure

A solution of 4-(methylthio)benzylazide (0.359 g, 2 mmol) in CH2Cl2 was cooled in ice and treated slowly with SO2Cl2 (0.297 g, 2.2 mmol). The reaction mixture was stirred at 5° C. for 1.5 h and then evaporated to dryness. The crude compound was obtained as a yellow oil.

Workup

  1. customevaporated to dryness

Sources & evidence

ORD record
ord-9fb9ef8bcf484da7b5714c0137e0e61e
Source dataset
uspto-grants-1992_05
Patent number
US05116833

Reaction notes

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