Benzoyl chloride → HCID 178486250, compound

HRID 1197297Notes

Reaction equation

HRID 1197297 reaction equation
[C:1]([NH:5][NH:6][PH:7]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1C)=[O:8])([CH3:4])([CH3:3])[CH3:2].[CH2:16](N(CC)CC)C.[C:23](Cl)(=[O:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>C(OCC)C.CCCCCC>[C:1]([N:5]([C:23](=[O:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)[N:6]([PH:7]([C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)=[O:8])[CH3:16])([CH3:2])([CH3:3])[CH3:4]

Participants

6

Reactant 3

HCID 7412Benzoyl chlorideHCID 8471TriethylamineHCID 178424407HCID 178424407, compound

Product 1

HCID 178486250HCID 178486250, compound

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

N'-t-butyl-N-(methylphenyl)phosphinylhydrazine (0.7 g) and triethylamine (3 ml) were stirred in diethyl ether (30 ml) at room temperature. Slowly, dropwise benzoyl chloride (1.2 g) was added to the reaction mixture. After stirring 1 hour at room temperature, the reaction mixture was diluted with hexane and the solid product filtered off. The white solid melted at 175°-178° C.

Workup

  1. filtrationthe solid product filtered off

Sources & evidence

ORD record
ord-e444ff44a35740538e9c8711ba2cf3a9
Source dataset
uspto-grants-1992_05
Patent number
US05117057

Reaction notes

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