HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 15657669, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | P,P-Diphenylphosphinic azide | HCID 199401 | — |
| Reactant | HCID 19107075 | HCID 19107075 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 15657669 | HCID 15657669 | 86.5% |
Reaction Steps
A solution of the compound from Example 44 (0.62 g, 2.4 mmol) and diphenylphosphorylazide (0.73 g, 2.64 mmol) in triethylamine (0.36 g) and 10 ml toluene was refluxed at 110° C. for 30 minutes. Workup and purification on silica gel gave the title compound (0.53 g, 86%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05276053 |
| Source dataset | uspto-grants-1994_01 |
| ORD ID | ord-53a87b4c40e24b06854b00535ef66862 |
| Source note | uspto-grants-1994_01 |