HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Tridecanone → N-[2,6-bis(1-methylethyl)phenyl]-3-oxo-tetradecanamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Tridecanone | HCID 11622 | — |
| Reactant | 2,6-Diisopropylphenyl isocyanate | HCID 92259 | — |
| Reactant | Lithium diisopropylamide | HCID 2724682 | — |
| Product | N-[2,6-bis(1-methylethyl)phenyl]-3-oxo-tetradecanamide | HCID 10476188 | 65% |
Reaction Steps
The title compound was prepared from 2-tridecanone (10.0 g, 0.050 mol), 2,6-diisopropylphenyl isocyanate (10.16 g, 0.050 mol) and lithium diisopropylamide (0.050 mol) using the procedure described in Example 1. Purification by flash chromatography (silica gel, 15% EtOAc/hexane) yielded 13.14 g (0.032 mol, 65%) of the desired product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05278326 |
| Source dataset | uspto-grants-1994_01 |
| ORD ID | ord-145ba8a02c4c410d8e4502e36c019625 |
| Source note | uspto-grants-1994_01 |