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HRID1198038

反应详情

EQUATION

反应方程式

HRID 1198038 的结构方程式

REACTANTS

反应物

3
结构：CCCCCCCCCCCC(C)=O
HCID11622

2-Tridecanone

C13H26O

结构：CC(C)c1cccc(C(C)C)c1N=C=O
HCID92259

2,6-Diisopropylphenyl isocyanate

C13H17NO

结构：CC(C)[N-]C(C)C.[Li+]
HCID2724682

2-Propanamine, N-(1-methylethyl)-, lithium salt

C6H14LiN

PRODUCTS

生成物

1
结构：CCCCCCCCCCCC(=O)CC(=O)Nc1c(C(C)C)cccc1C(C)C
HCID10476188

未命名化合物

收率 65%

PROCEDURE

实验过程

The title compound was prepared from 2-tridecanone (10.0 g, 0.050 mol), 2,6-diisopropylphenyl isocyanate (10.16 g, 0.050 mol) and lithium diisopropylamide (0.050 mol) using the procedure described in Example 1. Purification by flash chromatography (silica gel, 15% EtOAc/hexane) yielded 13.14 g (0.032 mol, 65%) of the desired product.

WORKUP

后处理

  1. customPurification by flash chromatography (silica gel, 15% EtOAc/hexane)