Octane → 5-(Dodecylsulfonyl)pentan-2-one

Participants

Reaction Steps

The title compound was prepared from 6-(dodecylsulfonyl)-3-oxo-hexanoic acid ethyl ester (2.30 g, 0.005 mol), 1,4-diazebicyclo[2.2.2]octane (6.60 g, 0.058 mol) and zylenes (10.7 ML, 15.0 eq) using the procedure described in Example 3, Step B. 1H NMR (ppm, CDCl3): 0.85-0.90 (t, 3H), 1.17-1.43 (m, 20H), 1.76-1.88 (m, 2H), 2.03-2.14 (m, 2H), 2.16 (s, 3H) 2.96-3.03 (m, 4H),

Provenance & Evidence