HCID 123850930, compound → HCID 54374062, compound

HRID 1198766Notes

Reaction equation

HRID 1198766 reaction equation
[CH3:1][SiH:2]([CH3:10])[N:3]([CH2:7][CH:8]=[CH2:9])[CH2:4][CH:5]=[CH2:6]>C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh].C1C=CC=CC=1>[CH:4]([N:3]1[CH2:7][CH2:8][CH2:9][Si:2]1([CH3:10])[CH3:1])=[CH:5][CH3:6]

Participants

4

Reactant 1

HCID 123850930HCID 123850930, compound

Product 1

HCID 54374062HCID 54374062, compoundYield 98%

Reagents, catalysts & solvents 2

HCID 84599Chlorotris(triphenylphosphine)rhodium(I)CatalystHCID 241BenzeneSolvent

Conditions

Temperature
80 °C

Procedure

Into a glass tube with an outside diameter of 10 mm and a length of 10 cm were introduced 2 mg RhCl(PPh3)3 and 2 mL of a mixture of 1 part N-dimethylsilyldiallylamine and 3 parts benzene, and the tube was sealed. After heating this for 17 hours at 80° C., the conversion was 100 weight % and 1-propenyl -2,2-dimethyl-1-aza-2-silacyclopentane was obtained in a yield of 98%. No production of 1-allyl-2,2,3-trimethyl-1-aza-2-silacyclobutane was observed.

Workup

  1. customthe tube was sealed

Sources & evidence

ORD record
ord-086c07101d3c40ada471d941a1a28bc5
Source dataset
uspto-grants-1994_01
Patent number
US05281736

Reaction notes

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