HCID 123850930, compound → HCID 54374062, compound

Participants

Reaction Conditions

Reaction Steps

Into a glass tube with an outside diameter of 10 mm and a length of 10 cm were introduced 2 mg RhCl(PPh3)3 and 2 mL of a mixture of 1 part N-dimethylsilyldiallylamine and 3 parts benzene, and the tube was sealed. After heating this for 17 hours at 80° C., the conversion was 100 weight % and 1-propenyl -2,2-dimethyl-1-aza-2-silacyclopentane was obtained in a yield of 98%. No production of 1-allyl-2,2,3-trimethyl-1-aza-2-silacyclobutane was observed.

Provenance & Evidence