Toluene → HCID 11074528, compound

HRID 1198767Notes

Reaction equation

HRID 1198767 reaction equation
[CH3:1][SiH:2]([CH3:14])[NH:3][CH2:4][CH:5]=[CH:6]CC1C=CC=CC=1.[C:15]1([CH3:21])[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[CH2:21]([N:3]1[CH2:4][CH2:5][CH2:6][Si:2]1([CH3:14])[CH3:1])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Participants

3

Reactant 2

HCID 1140TolueneHCID 131718323HCID 131718323, compound2×

Product 1

HCID 11074528HCID 11074528, compoundYield 96%

Procedure

Into a glass tube with an outside diameter of 10 mm and a length of 10 cm were introduced 5 mg ((1,5-cyclooctadiene)RhCl)2 and 2 mL of a mixture of 1 part N-dimethylsilyl-N-benzylallylamine and 2 parts toluene, and the tube was sealed. After this had been left quiescent for 30 minutes at room temperature, the conversion of N-dimethylsilyl-N-benzylallylamine was 100 weight %. 1-Benzyl-2,2-dimethyl-1-aza-2-silacyclopentane was obtained in a yield of 96%. No production of 1-benzyl-2,2,3-trimethyl-1-aza-2-silacyclobutane was observed.

Workup

  1. customthe tube was sealed

Sources & evidence

ORD record
ord-0f6012fd6b1c4d9da11929c1ce8f7cea
Source dataset
uspto-grants-1994_01
Patent number
US05281736

Reaction notes

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