Toluene → HCID 11074528, compound

Participants

Reaction Steps

Into a glass tube with an outside diameter of 10 mm and a length of 10 cm were introduced 5 mg ((1,5-cyclooctadiene)RhCl)2 and 2 mL of a mixture of 1 part N-dimethylsilyl-N-benzylallylamine and 2 parts toluene, and the tube was sealed. After this had been left quiescent for 30 minutes at room temperature, the conversion of N-dimethylsilyl-N-benzylallylamine was 100 weight %. 1-Benzyl-2,2-dimethyl-1-aza-2-silacyclopentane was obtained in a yield of 96%. No production of 1-benzyl-2,2,3-trimethyl-1-aza-2-silacyclobutane was observed.

Provenance & Evidence