Methane → HCID 19867719, compound

HRID 1198941Notes

Reaction equation

HRID 1198941 reaction equation
[CH3:1][C:2]1([CH3:24])[C:11]2[C:6](=[C:7]([CH3:22])[CH:8]=[C:9]([NH:12][C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=3[N+:19]([O-])=O)[CH:10]=2)[NH:5][C:4](=[O:23])[CH2:3]1.[H][H].C>>[CH3:1][C:2]1([CH3:24])[C:11]2[C:6](=[C:7]([CH3:22])[CH:8]=[C:9]([NH:12][C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=3[NH2:19])[CH:10]=2)[NH:5][C:4](=[O:23])[CH2:3]1

Participants

3

Reactant 2

HCID 297MethaneHCID 178428202HCID 178428202, compound

Product 1

HCID 19867719HCID 19867719, compound

Procedure

This compound, m.p. 90°, was prepared similarly to Preparation 17 using 3,4-dihydro-4,4,8-trimethyl-6-[(N-2-nitrophenyl)-amino]-2-(1H)-quinolone hydrogen and palladised charcoal as starting materials. The product was characterised spectroscopically and used directly in Example 14.

Sources & evidence

ORD record
ord-02eaa00dd4fd46cf8b6c35accd282454
Source dataset
uspto-grants-1990_02
Patent number
US04898872

Reaction notes

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