HRID1199156

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID4311764

Sodium borohydride (Na(BH4))

H4BNa

结构：C[C@H]1C[C@H]2[C@@H]3CC=C4CCCC[C@]4(C)[C@H]3CC[C@]2(C)C1=O

HCID54347812

未命名化合物

PRODUCTS

生成物

结构：C[C@H]1C[C@H]2[C@@H]3CC=C4CCCC[C@]4(C)[C@H]3CC[C@]2(C)[C@H]1O

HCID70359444

未命名化合物

PROCEDURE

实验过程

Sodium borohydride is added to the 16β-methly-5-androsten-17-one(produced in F hereinabove) according to the procedure described in Example 8F to form mostly the above-identified final product and a smaller amount of 16β-methly-5-androsten-17α-ol which are separated by HPLC on a silica gel column.